Properties of illuvial clay

 

Illuvial clay accumulations are characterised by specific features, both as regards their optical properties and the way they are distributed through the soil.

Optical properties

The clay particles, due to their size, remain outside the resolutionary power of the optic microscope. This is why they are not studied individually in micromorphology but are described in groups.

PPL (only polariser). Although on their own they are colourless, clay masses generally are yellowish in colour when the Fe+++ is present in a hydrated form. They are reddish if the Fe+++ content is high in anhydrous form, and only in hydromorphous soils (without any Fe+++ content or saturated with Fe++) they are greyish.

 

XPL (polariser + analyser) With the polarizer and analyser crossed, the clay masses should not show any anisotropy and therefore remain in extinction (black or dark grey), as although they are anisotropic crystals, due to their small size, the birefringence produced is minimal. On the other hand, as the thickness of a microscopic preparation is about 30 µm, the light will pass through many particles and as these are oriented at random, the different effects introduced by each tiny crystal will be compensate one another, finally annulling the optical effects.

 

Due to their laminar habit, however, the clay particles tend to be oriented parallel to one another. The result is that in a domain of oriented clay, the optical phenomena of each individual particle is added to those next to it, the domain acting as if it were a single crystal, showing distinctive optical properties: interference colour, extinction phenomena, etc.

 

 

Additionally, the definition of the extinction represents the degree of orientation of the clay particles.

Good orientation

Bad orientation

Kandites show low (grayish) interference colours, vermiculites and smectites higher colours of first or second order. Due to the presence of iron, abnormal yellow or red interference colours may appear.

 

 

Location

As illuvial clay accumulations occur due to the immobilisation of suspensions, they are localised, associated with larges pores, although in the dynamic horizons they could become part of the soil mass.

In general, they are found in the form of fairly films (think, median, thick) coating the walls of the macropores (PPL, XPL) and covering the aggregates and mineral grains or completely filling the voids.

 

 

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